Column Width

This web site builds the control from code behind but you could also grab it from the toolbox, this sample also uses a ViewModel to populate the properties of the control(s) in this sample.

sample image

View model

using System.Collections.ObjectModel;
using CommunityToolkit.Mvvm.ComponentModel;
using LiveChartsCore;
using LiveChartsCore.SkiaSharpView;
using LiveChartsCore.SkiaSharpView.Painting;
using SkiaSharp;

namespace ViewModelsSamples.Bars.Spacing;

public partial class ViewModel : ObservableObject
{
    public ISeries[] Series { get; set; } =
    {
        new ColumnSeries<double>
        {
            Values = new ObservableCollection<double> { 20, 50, 40, 20, 40, 30, 50, 20, 50, 40 },

            // Defines the distance between every bars in the series
            Padding = 0,

            // Defines the max width a bar can have
            MaxBarWidth = double.PositiveInfinity
        }
    };
}

Form code behind

using System.Windows.Forms;
using LiveChartsCore.SkiaSharpView.WinForms;
using ViewModelsSamples.Bars.Spacing;

namespace WinFormsSample.Bars.Spacing;

public partial class View : UserControl
{
    /// <summary>
    /// Initializes a new instance of the <see cref="View"/> class.
    /// </summary>
    public View()
    {
        InitializeComponent();
        Size = new System.Drawing.Size(50, 50);

        var viewModel = new ViewModel();

        var cartesianChart = new CartesianChart
        {
            Series = viewModel.Series,

            // out of livecharts properties...
            Location = new System.Drawing.Point(0, 0),
            Size = new System.Drawing.Size(50, 50),
            Anchor = AnchorStyles.Left | AnchorStyles.Right | AnchorStyles.Top | AnchorStyles.Bottom
        };

        Controls.Add(cartesianChart);
    }
}

Articles you might also find useful:

Cartesian chart control
Column series properties